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Volume 25: Optical Methods of Investigating Solid Bodies. 1965 ed.
・ISBN 978-1-4684-7208-0 paper EUR 49.99
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| 著者・編者 | Skobel tsyn, D. V. (ed.), |
|---|---|
| シリーズ | (The Lebedev Physics Institute Series) |
| 出版社 | (Springer-Verlag New York Inc., US) |
| 出版年月 | 2013 |
| ページ数 | 188 pp. |
| 言語 | ENG |
| ニュース番号 | <A05-54290> |
解説
The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 * SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi- lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec- tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre- 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re- 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.