株式会社極東書店トップ商品一覧Crystal Structure Determination: The Role of the Cosine Seminvariants. Softcover reprint of the original 1st ed. 1972

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Crystal Structure Determination: The Role of the Cosine Seminvariants. Softcover reprint of the original 1st ed. 1972

Crystal Structure Determination: The Role of the Cosine Seminvariants. Softcover reprint of the original 1st ed. 1972

・ISBN 978-1-4684-9956-8 paper EUR 49.99

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お気に入り
著者・編者Hauptman, H.,
出版社 (Springer-Verlag New York Inc., US)
出版年月2012
ページ数407 pp.
言語ENG
ニュース番号<A05-47082>

解説

The central theme of this monograph is that the cosine seminvariants are the key to crystal structures. The cosine seminvariants are the cosines of those linear combinations of the phases (the so-called structure seminvariants) whose values, for a given functional form for the geometric structure factor, are uniquely determined by the crystal structure alone and are there- fore independent of the choice of permissible origin. It follows that the cosine seminvariants themselves are uniquely determined, in general, by the observed magnitudes of the normalized structure factors. The values of the cosine seminvariants in turn lead unambiguously to the values of the individual phases and thus to the crystal structure by means of the E-map (Fourier synthesis). It is this property of the cosine seminvariants, that they serve to link the observed magnitudes with the desired phases of the normalized structure factors, which accounts for their importance and explains the emphasis which is here placed on their role.