株式会社極東書店トップ > 商品一覧 > Cooperative Phenomena in Jahn-Teller Crystals. Softcover reprint of the original 1st ed. 1995
商品詳細
Cooperative Phenomena in Jahn-Teller Crystals. Softcover reprint of the original 1st ed. 1995
・ISBN 978-1-4613-5755-1 paper EUR 49.99
¥13,361.- (税込) ※(※)価格はご注文時の参考価格となります。
納品価格につきましては書籍の入荷時点で確定となります。
版元の原価改定、外国為替の変動等により異なる場合がございますので、予めご了承下さい。
お気に入り
★★★
| 著者・編者 | Kaplan, Michael D. / Vekhter, Benjamin G., |
|---|---|
| シリーズ | (Modern Inorganic Chemistry) |
| 出版社 | (Springer-Verlag New York Inc., US) |
| 出版年月 | 2012 |
| ページ数 | 427 pp. |
| 言語 | ENG |
| ニュース番号 | <A04-77276> |
解説
This book by Kaplan and Vekhter brings together the molecular world of the chemist with the condensed matter world of the physicist. Prior to the collapse of the Soviet Union, chemists in the West devoted lit- to relationships between molecular electronic structure and tle attention solid-state vibronic phenomena. Treating quantum mechanical problems wherein the adiabatic Born-Oppenheimer approximation fails was done by "brute force. " With bigger and better computers available in the West, molecular orbital calculations were done on observed and conceived static structures with little concern for any cooperativity of vibrational behavior that might connect these states. While it had long been understood in the West that situations do occur in which different static structures are found for molecules that have identical or nearly identical electronic structures, little attention had been paid to understanding the vibrational states that could connect such structures. It was easier to calculate the electronic structure observed with several possible distortions than to focus on ways to couple electronic and vibrational behavior. In the former Soviet Union, computational power was not as acces- sible as in the West. Much greater attention, therefore, was devoted to conserving computational time by considering fundamental ways to han- dle the vibrational connectivity between degenerate or nearly degenerate electronic states.