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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes. Softcover reprint of the original 1st ed. 2017
・ISBN 978-3-319-84747-4 paper EUR 99.99
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| 著者・編者 | Hadlington, Terrance John, |
|---|---|
| シリーズ | (Springer Theses) |
| 出版社 | (Springer International Publishing AG, SZ) |
| 出版年月 | 2018 |
| ページ数 | 243 pp. |
| 言語 | ENG |
| ニュース番号 | ＜A04-62555＞ |
解説
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.