株式会社極東書店トップ商品一覧An Algebraic Approach to the Many-Electron Problem.

商品詳細

An Algebraic Approach to the Many-Electron Problem.

An Algebraic Approach to the Many-Electron Problem.

・ISBN 978-3-031-87827-5 paper EUR 44.99

¥12,025.- (税込) (※)価格はご注文時の参考価格となります。
納品価格につきましては書籍の入荷時点で確定となります。
版元の原価改定、外国為替の変動等により異なる場合がございますので、予めご了承下さい。

お気に入り
著者・編者Zamastil, Jaroslav / Uhlirova, Tereza,
シリーズ (SpringerBriefs in Physics)
出版社 (Springer International Publishing AG, SZ)
出版年月2025
ページ数71 pp.
言語ENG
ニュース番号<A04-337>

解説

This book presents an algebraic approach to the coupled cluster method for many-electron systems, pioneered by Josef Paldus. Using field methods along with an algebraic, rather than diagrammatic, approach facilitates a way of deriving the coupled cluster method which is readily understandable at the graduate level. The book begins with the notion of the quantized electron field and shows how the N-electron Hamiltonian can be expressed in its language. This is followed by introduction of the Fermi vacuum and derivation of the Hartree-Fock equations along with conditions for stability of their solutions. Following this groundwork, the book discusses a method of configuration interaction to account for dynamical correlations between electrons, pointing out the size-extensivity problem, and showing how this problem is solved with the coupled cluster approach. This is followed by derivation of the coupled cluster equations in spin-orbital form. Finally, the book explores practical aspects, showing how one may take advantage of permutational and spin symmetries, and how to solve coupled-cluster equations, illustrated by the Hubbard model of benzene, the simplest quasi-realistic model of electron correlation.